반응 #502131

ord-5726486e476e461186a9115a3428c48b

반응 방정식

CC1(C)OC[C@H](CO)O1
((4S)-2,2-dimethyl-1,3-dioxolan-4-yl)methan-1-ol
CC(C)(C)[Si](OC[C@@H](O)CO)(c1ccccc1)c1ccccc1
5b
CC(C)(C)[Si](OC[C@@H](O)CO)(c1ccccc1)c1ccccc1
(2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol
O=[N+]([O-])OC[C@@H](CO)O[N+](=O)[O-]
5d
O=[N+]([O-])OC[C@@H](CO)O[N+](=O)[O-]
(2R)-2,3-Bis(nitrooxy)propan-1-ol
→
O=[N+]([O-])OC[C@H](CO)O[N+](=O)[O-]
title compound
O=[N+]([O-])OC[C@H](CO)O[N+](=O)[O-]
(2S)-2,3-Bis(nitrooxy)propan-1-ol

반응물

—
5c
CC1(C)OC[C@H](CO)O1
((4S)-2,2-dimethyl-1,3-dioxolan-4-yl)methan-1-ol
CC(C)(C)[Si](OC[C@@H](O)CO)(c1ccccc1)c1ccccc1
5b
CC(C)(C)[Si](OC[C@@H](O)CO)(c1ccccc1)c1ccccc1
(2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol
O=[N+]([O-])OC[C@@H](CO)O[N+](=O)[O-]
5d
O=[N+]([O-])OC[C@@H](CO)O[N+](=O)[O-]
(2R)-2,3-Bis(nitrooxy)propan-1-ol

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

The title compound was prepared in four steps from ((4S)-2,2-dimethyl-1,3-dioxolan-4-yl)methan-1-ol following the procedures for Examples 5a, 5b, 5c, and 5d.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US08088762B2uspto-grants-2012_01