반응 #502064

ord-7e11e4253b7d44f2a2c4ac9c3e72ef63

반응 방정식

O=C([O-])[O-].[Ag+2]
Silver carbonate
O=S(=O)(O)CS(=O)(=O)O
methanedisulfonic acid
O=C([O-])[O-].[Ag+2]
silver carbonate
O=C=O
carbon dioxide
→
O=S(=O)([O-])CS(=O)(=O)[O-].[Ag+2]
silver methanedisulfonate
수율 123.7%

반응물

O=C([O-])[O-].[Ag+2]
Silver carbonate
O=S(=O)(O)CS(=O)(=O)O
methanedisulfonic acid
O=C([O-])[O-].[Ag+2]
silver carbonate
O=C=O
carbon dioxide

시약

없음

용매

O
water

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타any remaining insoluble material was removed by filtration
  2. 2
    기타was removed under vacuum

실험 절차

Silver carbonate (20 g, 0.0725 moles) was added to methanedisulfonic acid (25.55 g 50% solution in water) and diluted in 25 mL of distilled water while stirring. The silver carbonate dissolved with effervescence of carbon dioxide. After the reaction was complete, any remaining insoluble material was removed by filtration and the filtrate was stripped of water was removed under vacuum to give 25.3 g of pure silver methanedisulfonate.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US08088548B2uspto-grants-2012_01