반응 #48893

반응 방정식

vinyl acetate

vinyltriethylsilane

triethylsilane

→

tetraethylsilane

triethylsilanol

용매

toluene

반응 조건

후처리

1. 1
   기타In a reactor were placed
2. 2
   workup.ADDITIONwas added
3. 3
   workup.WAITa reaction was carried out at 40° C. for one hour
4. 4
   기타After the reaction

실험 절차

In a reactor were placed di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [IrCl(cod)]2 (0.05 mmol), vinyl acetate (20 mmol), and toluene (3 ml). The mixture was raised in temperature to 40° C. in a nitrogen atmosphere, triethylsilane (Et3SiH) (5 mmol) was added thereto over one hour, and a reaction was carried out at 40° C. for one hour. After the reaction, the reaction mixture was analyzed by gas chromatography to find that vinyltriethylsilane was produced in a yield of 36% and tetraethylsilane and acetic ester of triethylsilanol were by-produced in yields of 7% and 12%, respectively.

출처