반응 #48892

반응 방정식

vinyltriethylsilane

triethylsilane

vinyl acetate

→

tetraethylsilane

triethylsilanol

용매

toluene

반응 조건

후처리

1. 1
   기타In a reactor were placed
2. 2
   기타After the reaction

실험 절차

In a reactor were placed triethylsilane (Et3SiH) (5 mmol), di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [IrCl(cod)]2 (0.05 mmol), vinyl acetate (20 mmol), and toluene (3 ml), and a reaction was conducted at 40° C. in a nitrogen atmosphere for one hour. After the reaction, the reaction mixture was analyzed by gas chromatography to find that vinyltriethylsilane was produced in a yield of 20%, and tetraethylsilane and acetic ester of triethylsilanol were by-produced in yields of 9% and 14%, respectively.

출처