반응 #487496

반응 방정식

tetra(4-carboxyphenyl)porphine

pyridine

isobutyl chloroformate

→

Porphyrin

용매

DMSO

DMSO

반응 조건

후처리

1. 1
   기타The synthesis was performed in a three-necked flask under nitrogen
2. 2
   workup.ADDITIONwas added
3. 3
   workup.ADDITIONThe reaction mixture was mixed at 70° C. for 4 hours
4. 4
   기타The product obtained
5. 5
   여과was filtered on a Buchner funnel with a sintered glass disc
6. 6
   세척washed with methanol till the transparent filtrate
7. 7
   기타was obtained
8. 8
   기타the product was dried in a vacuum dryer
9. 9
   기타A green powder was obtained

실험 절차

The synthesis was performed in a three-necked flask under nitrogen. 50 mg of mezo-tetra(4-carboxyphenyl)porphine (4CP) was dissolved in 5 ml of dry DMSO, the catalysts, i.e. 120 μl of pyridine and 30 μl of isobutyl chloroformate, were added and after 5 minutes a suspension of 0.5 g Cloisite 30 B in 15 ml of dry DMSO was added. The reaction mixture was mixed at 70° C. for 4 hours. The product obtained was filtered on a Buchner funnel with a sintered glass disc and washed with methanol till the transparent filtrate was obtained and then the product was dried in a vacuum dryer. A green powder was obtained.

출처