반응 #487111

반응 방정식

ethyl chloride

sodium

N-hydroxyhexahydrophthalimide

ethyl chloride

→

N-ethoxyhexa-hydrophthalimide

수율 79.4%

반응 조건

후처리

1. 1
   온도was maintained at 100° C
2. 2
   추출The reaction product was extracted from the mixture with toluene
3. 3
   추출Gas chromatographic analysis of the toluene extract

실험 절차

In an autoclave 60 g of a 20 wt % solution of the sodium salt of N-hydroxyhexahydrophthalimide (0.063 mol) and 5.0 g (0.078 mol) of ethyl chloride were mixed together. The mixture was heated to 100° C. After reaching this temperature the mixture was stirred for a further 5 hours while the temperature was maintained at 100° C. After 5 hours' reaction the excess ethyl chloride was blown out and the reaction mixture was discharged. The reaction product was extracted from the mixture with toluene. Gas chromatographic analysis of the toluene extract showed that the yield was 79% of N-ethoxyhexa-hydrophthalimide (0.050 mol).

출처