반응 #486477

반응 방정식

(Tetramethylcyclopentadienyl)(diphenylmethyl)dimethylsilane dipotassium salt

zirconium tetrachloride

→

desired product

(tetramethylcyclopentadienyl)(diphenylmethyl)dimethylsilane zirconium dichloride

용매

toluene

반응 조건

후처리

1. 1
   여과filtered
2. 2
   기타The solvent was removed under vacuum
3. 3
   세척The residue was washed with hexane
4. 4
   여과filtered
5. 5
   세척washed again with hexane
6. 6
   기타dried

실험 절차

(Tetramethylcyclopentadienyl)(diphenylmethyl)dimethylsilane dipotassium salt (3.00 g, 7.10 mmol) was combined with 1.654 grams of zirconium tetrachloride in 150 mL of toluene at about 25° C. The reaction mixture was stirred overnight at about 25° C., and then filtered. The solvent was removed under vacuum. The residue was washed with hexane and filtered, washed again with hexane and dried to give the desired product as a red-orange solid.

출처