반응 #481607

반응 방정식

l-bromo-2-butanone

pentamethylene sulfide

→

2-oxobutyl-thiacyclohexanium bromide

수율 72.7%

용매

acetone

반응 조건

후처리

1. 1
   기타After leaving for 24 hours
2. 2
   여과the deposited white crystal was collected by filtration
3. 3
   세척was washed with ether
4. 4
   기타The powder was dried by a vacuum drier at 30° C. for six hours

실험 절차

In a 100 ml three-necked flask, 4 g of pentamethylene sulfide was dissolved in 40 ml of acetone. To the solution, 6 g of l-bromo-2-butanone was added dropwise while stirring. After leaving for 24 hours, the deposited white crystal was collected by filtration. The white crystal was ground to a powder, which was washed with ether. The powder was dried by a vacuum drier at 30° C. for six hours to obtain 7.2 g of 2-oxobutyl-thiacyclohexanium bromide (yield: 72.5%).

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