반응 #474156

반응 방정식

Cyclohexane-1,2-dione

2,6-diisopropylaniline

formic acid

→

title compound

수율 51.8%

(E)-N-(2-(2,6-diisopropylphenylamino)cyclohex-2-enylidene)-2,6-diisopropylaniline

수율 51.8%

용매

methanol

반응 조건

후처리

1. 1
   기타Synthesis
2. 2
   기타Precipitated white crystalline solid
3. 3
   기타is collected on the frit
4. 4
   세척washed with methanol (2×15 mL)
5. 5
   기타dried under reduced pressure
6. 6
   기타to give

실험 절차

Synthesis based on literature procedure (Gates, D. P.; Svejda, S. A. Onate, E.; Killian, C. M.; Johnson, L. K.; White, P. S.; Brookhart M. Macromolecules, 2000; 33:2320-2334.). Cyclohexane-1,2-dione (2.062 g, 18.39 mmol) and 2,6-diisopropylaniline (6.52 g, 36.78 mmol) are dissolved in 70 mL of methanol. To this solution is added 1 mL of formic acid and the mixture is stirred for 3 days at room temperature. Precipitated white crystalline solid is collected on the frit, washed with methanol (2×15 mL) and dried under reduced pressure to give 4.1 g (51.8% yield) of title compound of Preparation 1.

출처