반응 #467450

반응 방정식

1,3-dihydroxyadamantane

acetic acid-acetic anhydride

hydroxyadamantane

→

1,3,5-trihydroxyadamantane

반응 조건

후처리

1. 1
   온도with heating
2. 2
   기타the reaction for 8 hours
3. 3
   기타to obtain
4. 4
   기타This mixture was partitioned by high performance liquid chromatography

실험 절차

One mol of 1,3-dihydroxyadamantane was stirred in an acetic acid-acetic anhydride solution of CrO3, oxidizing agent, with heating. After carrying out the reaction for 8 hours, the reaction solution was neutralized to obtain a mixture of polyhydroxylated compounds of hydroxyadamantane. This mixture was partitioned by high performance liquid chromatography to obtain 1,3,5-trihydroxyadamantane.

출처