반응 #451341

ord-315fd0e0fe13428fa1ac09c97485c2f1

반응 방정식

C=CN1CCCC1=O
N-vinylpyrrolidone
C=C(C)C(=O)OC(C)(C)C
tert-butyl methacrylate
CC(C[*:1])[*:2]
polypropylene
CC(C)(C#N)N=NC(C)(C)C#N
azobisisobutyronitrile
C=CCOC(=O)C(=C)C
allyl methacrylate

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    workup.ADDITIONwas added to the mixture

실험 절차

The dimer of allyl methacrylate, which was prepared according to Example 1, was added to the mixture containing 80 wt.-% N-vinylpyrrolidone and 20 wt.-% tert-butyl methacrylate in the amount of 1 wt.-% on the whole mixture. The mixture was polymerized in a polypropylene mold at 60° C. for 16 h in the presence of 0.4 wt.-% azobisisobutyronitrile. The resulting gel contained, after swelling with water, 67 wt.-% water at G=0.529 MPa.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04604440uspto-grants-1986_08