반응 #445801

ord-d5c0e32b8e5c4f339814a1b6d66005ad

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    온도the resulting solution was heated
  2. 2
    온도at reflux for 3.5 hours
  3. 3
    온도The solution was cooled
  4. 4
    여과The precipitate was collected by filtration
  5. 5
    기타recrystallised from ethanol-water

실험 절차

Methyl 7-phthalimidohept-5-ynoate (1.45 g) was dissolved in a mixture of concentrated hydrochloric acid (7.3 ml), acetone (30 ml) and water (14.6 ml) and the resulting solution was heated at reflux for 3.5 hours. The solution was cooled and then poured into water (175 ml). The precipitate was collected by filtration and recrystallised from ethanol-water to give the title compound (1.12 g) m.p. 120°-122° C.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04997847uspto-grants-1991_03