반응 #44450

반응 방정식

2,6-dibromoaniline

salicylaldehyde

triethylamine

→

2-[(2,6-dibromophenyl)iminomethyl]phenol

수율 109.8%

용매

toluene

반응 조건

후처리

1. 1
   온도to reflux in a Dean-Stark apparatus for 2 h
2. 2
   기타was evaporated

실험 절차

A solution of 2,6-dibromoaniline (9 g, 35.9 mmol), salicylaldehyde (2.79 mL, 35.9 mmol) and p-toluenesulfonic acid (20 mg, 0.1 mmol) in toluene (180 mL) was heated to reflux in a Dean-Stark apparatus for 2 h. After adding some triethylamine the reaction mixture was evaporated resulting in crude compound 2-[(2,6-dibromophenyl)iminomethyl]phenol (14 g, 100%).

출처