반응 #443883

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3-t-butylperoxy-1,3-dimethylbutanol

oxalyl chloride

oxalyl chloride

→

3-t-butylperoxy-1,3-dimethylbutyl chlorooxalate

수율 98.5%

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실험 절차

In this example the product was prepared in two synthetic steps. In the first step 3-t-butylperoxy-1,3-dimethylbutanol was reacted with 100% molar excess of oxalyl chloride. Upon completion of the reaction the excess oxalyl chloride was stripped from the product at reduced pressure to produce 3-t-butylperoxy-1,3-dimethylbutyl chlorooxalate having an assay of 97.5% and in a corrected yield of 98.5%. In the second step 3-t-butylperoxy-1,3-dimethylbutyl chlorooxalate was reacted with 2,5-dimethyl-2,5-dihydroperoxyhexane, in the presence of pyridine, to yield the product as described below:

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