반응 #442750

ord-eed7f6c0c9704090aaf4de213e18c8fa

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

2-Methyl-3-buten-2-ol, 2-propanol and tert.-butyl peroxy pivalate (75% solution in aliphates) are reacted in a molar ratio of 1:15:0.3 at 90° C. and a pressure of 500 kPa as described in example 1. After a contact period of 20 minutes of the reaction mixture in a tube reactor 95% of the olefin used has been converted. 2,5-dimethylhexane-2,5-diol is formed with a selectivity of 76%.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05831134uspto-grants-1998_11