반응 #43978

반응 방정식

2-(2,3,4,5-tetramethylcyclopentadienyl)benzyloxytitanium bis(dimethylamide)

trimethylchlorosilane

→

2-(2,3,4,5-Tetramethylcyclopentadienyl)benzyloxytitanium dichloride

수율 94.3%

용매

pentane

pentane

반응 조건

실험 절차

To a solution of 2-(2,3,4,5-tetramethylcyclopentadienyl)benzyloxytitanium bis(dimethylamide) (0.84 g, 3.1 mmol) in pentane (15.2 mL) was added dropwise a solution of trimethylchlorosilane (3.67 g, 33.8 mmol) in pentane (5.0 mL) at 0° C. The mixture was stirred at room temperature for 15 hrs. 2-(2,3,4,5-Tetramethylcyclopentadienyl)benzyloxytitanium dichloride (1.00 g, yield 94.3%) was obtained as an yellow solid.

출처