반응 #430112

ord-a287f31b9303459e8fd267ab8b600b01

반응 방정식

COc1ccc2cc([C@H](C)C(=O)O)ccc2c1
(S)-2-(6-methoxy-2-naphthyl)propionic acid
[Na+].[OH-]
sodium hydroxide
COc1ccc2cc([C@H](C)C(=O)[O-])ccc2c1.[Na+]
naproxen sodium

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

It has been found that, surprisingly, when neutralizing (S)-2-(6-methoxy-2-naphthyl)propionic acid having a chiral purity below 99% with less than a stoichiometric amount of aqueous sodium hydroxide solution to form naproxen sodium, it is possible to increase the chiral purity of the naproxen sodium to 99% or more by removing the water by use of a suitable organic solvent, or simply by distilling off water from an aqueous solution.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05859292uspto-grants-1999_01