반응 #429148

ord-24eadf45c8c849a6a1c06f8f116ccb3e

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

A process for producing 2-hydroxy-3-pinanone, comprising the steps of reacting α-pinene with catalytic potassium osmate in solution of pyridine, N-methylmorpholine-N-oxide and aqueous acetone to produce cis-pinanediol; and thereafter oxidizing said cis-pinanediol with DMSO activated by pyridine.SO3 and triethylamine in an appropriate solvent to produce 2-hydroxy-3-pinanone.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05856497uspto-grants-1999_01