반응 #42774

ord-d432949c0c7046e1843b5cf1467f7cf1

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    세척washed with water (3×100 ml) and saturated brine (50 ml)
  2. 2
    건조dried (MgSO4)
  3. 3
    여과filtered
  4. 4
    기타the filtrate is evaporated
  5. 5
    기타to give a pale pink solid

실험 절차

3-(4-Chlorophenyl)-7-hydroxy-2-isopropyl-chromen-4-one (2.3 g, 7.31 mmol) is suspended in dry dichloromethane (140 ml) at room temperature. N-iodosuccinimide (1.73 g, 7.67 mmol) is added, and the mixture is stirred vigorously at room temperature for 30 min. The mixture is diluted with dichloromethane (60 ml), washed with water (3×100 ml) and saturated brine (50 ml), dried (MgSO4) and filtered, and the filtrate is evaporated to give a pale pink solid.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07732435B2uspto-grants-2010_06