반응 #417918

반응 방정식

lithium aluminum hydride

15

methyl 3-(undec-4Z-enyloxy)benzoate

→

colorless oil

수율 99.9%

3-(undec-4Z-enyloxy)benzyl alcohol

수율 99.9%

용매

ether

ether

반응 조건

후처리

1. 1
   기타After reaction for 1 hour 30 minutes
2. 2
   여과After filtering through Celite
3. 3
   건조drying over Na2SO4
4. 4
   농축concentrating

실험 절차

35 mg of lithium aluminum hydride (922 μmol) are added, at 0° C., to 140 mg of 15 (460 μmol) in ether (3 mL). After reaction for 1 hour 30 minutes, the reaction medium is diluted with ether and hydrolyzed with two drops of water. After filtering through Celite, drying over Na2SO4 and concentrating, 127 mg of a colorless oil are isolated, i.e. a yield of 99%.

출처