반응 #4078

반응 방정식

N-cyclohexyl-4-nitrosoaniline

NaOH

n-hexanol

→

N-cyclohexyl-p-phenylenediamine

반응 조건

후처리

1. 1
   기타equipped with stirrer, condenser
2. 2
   온도thermometer, and heated
3. 3
   온도Heating
4. 4
   기타to rise to 115° C.
5. 5
   workup.ADDITIONdropped, within 10 minutes, to 100° C
6. 6
   온도With the application of heat
7. 7
   온도a temperature of 90°-95° C. was maintained for 30 minutes

실험 절차

51.0 g (0.25 mole) N-cyclohexyl-4-nitrosoaniline, 20.0 g (50%) NaOH and 135 g n-hexanol were charged to a 0.5 liter three-necked round bottom flask equipped with stirrer, condenser and thermometer, and heated while stirring to 95° C. until the development of an exotherm was observed. Heating was discontinued, the reaction temperature continued to rise to 115° C. and then dropped, within 10 minutes, to 100° C. With the application of heat, a temperature of 90°-95° C. was maintained for 30 minutes. The reaction mixture contained no unreacted nitroso compound. The yield of the product was 64 wt. %; m.p. 59°-61° C.

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