반응 #4044

반응 방정식

perfluoro-2-methyl-3-oxahexanoyl fluoride

sodium trimethylsilanolate

→

Sodium perfluoro-2-methyl-3-oxahexanoate

수율 77.3%

용매

o-dichlorobenzene

반응 조건

후처리

1. 1
   기타at room temperature
2. 2
   온도by rapid heating to 150°

실험 절차

The procedure of Example 1 was followed using perfluoro-2-methyl-3-oxahexanoyl fluoride (16.6 g, 50 mmol), sodium trimethylsilanolate (5.6 g, 50 mmol), dry o-dichlorobenzene (200 mL), and 1 h at room temperature followed by rapid heating to 150°. Sodium perfluoro-2-methyl-3-oxahexanoate (13.6 g, 77% yield) was isolated as a white solid: The 19F NMR data were the same as reported in Example 15.

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