반응 #4037

반응 방정식

methyl 4-chlorobenzoate

sodium trimethylsilanolate

→

Sodium 4-chlorobenzoate

수율 94.7%

용매

toluene

반응 조건

후처리

1. 1
   온도of heating at 80°

실험 절차

The procedure of Example 1 was followed using methyl 4-chlorobenzoate (4.55 g, 26.6 mmol), sodium trimethylsilanolate (2.99 g, 26.6 mmol), dry toluene (150 mL), and 4 h of heating at 80°. Sodium 4-chlorobenzoate (4.50 g, 86% yield) was isolated as a white solid: 1H NMR (D2O, DSS, 80 MHz) δ 7.65 ppm (ABq, Δν1-3 =29 Hz, J=8 Hz, Ar--H's, 4H).

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