반응 #40264

반응 방정식

1,2-dimethyl-1H-benzimidazole

N,N′-(disulfanediyldiethane-2,1-diyl)bis(2-chloroacetamide)

→

white powder

수율 129.8%

1,1′-{disulfanediylbis[ethane-2,1-diylimino(2-oxoethane-2,1-diyl)]}bis(2,3-dimethyl-1H-benzimidazol-3-ium) chloride

수율 129.8%

용매

acetonitrile

반응 조건

후처리

1. 1
   온도was heated
2. 2
   온도to reflux for 24 h
3. 3
   온도After cooling
4. 4
   여과the resulting white solids were collected by filtration
5. 5
   세척washed with ethyl acetate and dichloromethane

실험 절차

A mixture of compound 1,2-dimethyl-1H-benzimidazole (2.93 g, 20 mmol) and N,N′-(disulfanediyldiethane-2,1-diyl)bis(2-chloroacetamide) (1.53 g, 5 mmol) in 20 ml of acetonitrile was heated to reflux for 24 h. After cooling, the resulting white solids were collected by filtration and washed with ethyl acetate and dichloromethane to afford 1.94 g of a white powder. Analyses were in accordance with the expected structure.

출처