반응 #3842
ord-950cfed0e8884a9ab3f2f0fdcbee3869
반응 방정식
반응 조건
상세 조건
See reaction.notes.procedure_details.
후처리
- 1온도refluxed for 16 hours
- 2온도The solution was cooled
- 3농축concentrated in vacuo
- 4기타leaving a yellow liquid
- 5기타The crude product was purified
실험 절차
To a solution of 2-mercaptobenzophenone (2.3 g, 7.4 mmol) in diethyl ether (10 mL) was added dropwise diethyl azodicarboxylate (0.65 g, 3.7 mmol). The solution was stirred for 5 minutes at room temperature, then diluted with benzene (40 mL) and refluxed for 16 hours. The solution was cooled and concentrated in vacuo leaving a yellow liquid. The crude product was purified using silica gel chromatography (75% hexane/25% ethyl acetate) to give the title compound as a yellow foam (0.8 g, 50%);