반응 #3832

ord-3891158d65564d66834bcdc1c2f37155

반응 방정식

O=C(Cl)c1ccccc1SSc1ccccc1C(=O)Cl
2,2'-dithiobisbenzoyl chloride
NC1CC1
cyclopropylamine
CCN(CC)CC
triethylamine
ClCCl
dichloromethane
ClCCl
dichloromethane
O=C(NC1CC1)c1ccccc1SSc1ccccc1C(=O)NC1CC1
title compound
O=C(NC1CC1)c1ccccc1SSc1ccccc1C(=O)NC1CC1
2,2'-Dithiobis(N-cyclopropylbenzamide)

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타A solid formed immediately
  2. 2
    여과filtered
  3. 3
    기타The solid was dried

실험 절차

A solution of 2,2'-dithiobisbenzoyl chloride (1.0 g, 3.0 mmol) in 20 mL of dichloromethane was added dropwise to a solution of cyclopropylamine (0.52 mL, 7.5 mmol) and triethylamine (1.2 mL, 9.0 mmol) in 20 mL of dichloromethane. A solid formed immediately, the mixture was stirred for 3 hours and then filtered. The solid was dried to yield 0.65 g of the title compound, mp 257°-259° C.;

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05734081uspto-grants-1998_03