반응 #366620

ord-550de413773c49dd9b5b621e9b040826

반응 방정식

C1COCCOCCOCCOCCO1
15-crown-5
O=C(Cl)Oc1ccccc1
phenylchloroformate
[F-].[Na+]
sodium fluoride
O=C(F)Oc1ccccc1
Phenylfluoroformate

반응 조건

온도
40°CELSIUS
상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타Reaction completion

실험 절차

To a solution of phenylchloroformate in acetonitrile is charged sodium fluoride. To this mixture is charged the 15-crown-5(“15C5”) at ambient temperature. The reaction mixture is then heated to 40° C. for approximately 16 hrs. Reaction completion is monitored by gas chromatography (“G.C.”).

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US06362363B1uspto-grants-2002_03