반응 #359159

ord-77ab20320a8d45b2b2661899ce53e347

반응 방정식

C[Si](C)(C)Cl
trimethylchlorosilane
BrC1=Cc2ccccc2C1
2-bromoindene
[Mg]
magnesium
C1=Cc2ccccc2C1.[Mg][Br]
Bromomagnesium indene
C[Si](C)(C)C1=Cc2ccccc2C1
2-trimethylsilylindene

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

Bromomagnesium indene was prepared from 10.0 g (51.3 mmol) of 2-bromoindene and 5 g of magnesium in a nitrogen stream. The reaction product was reacted with 6.5 ml of trimethylchlorosilane to obtain 7.14 g (37.9 mmol) of 2-trimethylsilylindene as a colorless oily product.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07453005B2uspto-grants-2008_11