반응 #353000

반응 방정식

diphenylphosphine oxide

indium chloride

→

diphenylphosphine

수율 88.0%

반응 조건

후처리

1. 1
   workup.DISTILLATIONDiphenylphosphine distills off through a descending condenser at a transition temperature of 132° C
2. 2
   온도After a total of 2 hours, the internal temperature has been raised to 195° C

실험 절차

172 g (0.852 mol) of diphenylphosphine oxide and 0.8 g of indium chloride are mixed and heated to 152° C., the pressure being reduced simultaneously (8 mbar). Diphenylphosphine distills off through a descending condenser at a transition temperature of 132° C. After a total of 2 hours, the internal temperature has been raised to 195° C. 70 g of diphenylphosphine are obtained. That corresponds to a yield of 88% of theory.

출처