반응 #350549

ord-d7990f7b93cc4b68a753a37835072594

반응 방정식

c1ccncc1
Pyridine
CCCCCl
n-butyl chloride
C1COCCO1
dioxane
CCCC[n+]1ccccc1.[Cl-]
butylpyridinium chloride

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    온도cooled
  2. 2
    기타precipitating the crystals
  3. 3
    기타formed

실험 절차

Pyridine and excess n-butyl chloride were heated under reflux in nitromethane for 24 hours and then cooled, and the reaction solution was poured into dioxane, thereby precipitating the crystals formed. Thus, crude crystals of butylpyridinium chloride (BPC) were obtained. These were purified by recrystallizing them in methanol/dioxane solvent two or three times and then fully dried in vacuum.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05643490uspto-grants-1997_07