반응 #349176

ord-d7a51cd389d24459ace4c698426a2e68

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    온도to maintain a stirrable slurry
  2. 2
    온도after which the mixture was cooled
  3. 3
    세척The resulting solid was washed with ether
  4. 4
    기타recrystallized from acetone/methanol

실험 절차

A mixture of 4.0 g of cis-2-phenylcyclopentylamine hydrochloride, M.P. 205°-206° C. and 5.0 ml of O-methylcaprolactim was allowed to stand at room temperature for 6 days with occasional stirring. A few drops of ethanol were added to maintain a stirrable slurry, after which the mixture was cooled. The resulting solid was washed with ether and recrystallized from acetone/methanol to give the desired product, M.P. 181.5°-183.5° C. (dec.).

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04153235uspto-grants-1979_05