반응 #335342

ord-1b159444d1244d48bc290c258391c5e9

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타the solvent is removed
  2. 2
    기타the residue evaporated with toluene several times

실험 절차

To a moisture protected solution of 28.4 ml of phosphorous oxychloride in 200 ml of carbon tetrachloride is added dropwise with stirring a solution of 50 g of 1-hexadecanol in 125 ml of carbon tetrachloride. After stirring at ambient temperature for 18 hours, the solvent is removed and the residue evaporated with toluene several times to give 71 g of the desired product as a vacuum dried water white oil.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05208223uspto-grants-1993_05