반응 #335080

ord-bfd6fac7dafe43f0b928d2622cad077d

반응 방정식

ClCCl
methylene chloride
B#B
diborane
c1ccncc1
pyridine
ClC(Cl)Cl
chloroform
O=C([O-])O.[Na+]
sodium bicarbonate
CCCCCCCCCCN
amine 10

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

An alternative synthesis of 10 can be accomplished by first reacting the amine 6 with a suitable carboxylic acid (as a melt) or with an acid chloride in an inert solvent such as methylene chloride, chloroform, ether or toluene and with a base such as triethylamine, pyridine or sodium bicarbonate present. The intermediate amide is then reduced with a suitable reagent such as diborane in an inert solvent such as ether, tetrahydrofuran (THF), dioxane or dimethoxyethane to afford the desired amine 10.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05208252uspto-grants-1993_05