반응 #334899

ord-ebfbf94f624d48f287be4b52346279fa

반응 방정식

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
수율 100.0%
O=C=O
carbon dioxide
수율 17.8%

반응 조건

온도
160°CELSIUS
상세 조건
See reaction.notes.procedure_details.

실험 절차

A 50:1 mole ratio of ethylene carbonate to diethylene glycol is heated with stirring under a nitrogen atmosphere for 45 hours at 160° C. using 1.0 percent sodium metaborate as catalyst to give 100 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 17.8 percent carbon dioxide. The catalyst is removed as in Example 1.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04709069uspto-grants-1987_11