반응 #334891

ord-d55c128e493543ae96f7edf2646d3d77

반응 방정식

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
수율 97.5%
O=C=O
carbon dioxide
수율 23.7%

반응 조건

온도
175°CELSIUS
상세 조건
See reaction.notes.procedure_details.

실험 절차

A 10:1 mole ratio of ethylene carbonate and diethylene glycol is heated with stirring under a nitrogen atmosphere for 3 hours at 175° C. using 0.5 percent Na2SnO3.3H2O as catalyst to give 97.5 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 23.7 percent carbon dioxide. The catalyst is removed as in Example 1.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04709069uspto-grants-1987_11