반응 #334889

ord-2c5f41d7c6974a6e82f3a5e8b4cec75f

반응 방정식

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
수율 96.6%
O=C=O
carbon dioxide
수율 27.6%

반응 조건

온도
135°CELSIUS
상세 조건
See reaction.notes.procedure_details.

실험 절차

A 50:1 mole ratio of ethylene carbonate:monoethylene glycol is heated with stirring under a nitrogen atmosphere for 88 hours at 135° C. using 0.2 percent Na2SnO3.3H2O as catalyst to give 96.6 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 27.6 percent carbon dioxide.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04709069uspto-grants-1987_11