반응 #328496

반응 방정식

9-decen-1-ol

K2CO3

bis(pentafluoroethyl)phosphinous acid chloride

(C2F5)2PCl

→

9-Decenyl bis(pentafluoroethyl)phosphinite

용매

CH2Cl2

반응 조건

후처리

1. 1
   기타condensed in
2. 2
   여과the precipitate is filtered off
3. 3
   기타volatile substances are removed in vacuo

실험 절차

0.31 g (1.9 mmol) of 9-decen-1-ol is initially introduced in CH2Cl2 with excess K2CO3, and 0.64 g (2.1 mmol) of bis(pentafluoroethyl)phosphinous acid chloride, (C2F5)2PCl, is condensed in. After the mixture has been stirred at room temperature for 30 minutes, the precipitate is filtered off, and volatile substances are removed in vacuo. The product, 9-decenyl bis(pentafluoroethyl)phosphinite, remains as a colourless, oily liquid, which is characterised by spectroscopy.

출처