반응 #327946

반응 방정식

Tributyl(1-propynyl)tin

benzyl azide

→

title compound

1-Benzyl-5-methyl-4-(tributylstannyl)-1H-1,2,3-triazole

반응 조건

후처리

1. 1
   기타The mixture was purified by silica gel chromatography
2. 2
   세척eluting with a gradient of 5-40% ethyl acetate in hexanes

실험 절차

Tributyl(1-propynyl)tin (3.87 g, 11.8 mmol) and benzyl azide (2.2 mL, 17.6 mmol) were combined and heated to 150° C. overnight. The mixture was purified by silica gel chromatography eluting with a gradient of 5-40% ethyl acetate in hexanes to afford the title compound. MS (ESI+) m/z 464.2 (M+H)+.

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