반응 #326378

반응 방정식

1-butyl-3-methylimidazolium chloride

1,4-butane sultone

→

1-butyl-3-methylimidazolium 4-chlorobutylsulfonate

반응 조건

후처리

1. 1
   workup.DISTILLATIONThe excess of 1,4-butane sultone was distilled off in vacuum
2. 2
   기타the residue was dried overnight at 50° C. in high vacuum (1·10−3mbar)

실험 절차

The mixture of equivalent of 1-butyl-3-methylimidazolium chloride and 20 equivalents of 1,4-butane sultone is stirred at 40° C. (temperature in the oil-bath) for 24 hours). The excess of 1,4-butane sultone was distilled off in vacuum and the residue was dried overnight at 50° C. in high vacuum (1·10−3mbar). Liquid 1-butyl-3-methylimidazolium 4-chlorobutylsulfonate is obtained in close to quantitative yield. The material was characterized by NMR spectroscopy.

출처