반응 #324098

반응 방정식

norbornene

acrolein

→

3-oxa-tricyclo[6.2.1.02,7 ]undec-4-ene

수율 50.0%

반응 조건

후처리

1. 1
   기타After evaporation
2. 2
   workup.DISTILLATIONa fractional distillation of the residue

실험 절차

56.4 g of norbornene, 16.8 g of acrolein and 0.5 g of hydroquinone were heated 15 hours at 190° in a stainless steel autoclave (pressure about 15 atm.). After evaporation a fractional distillation of the residue gave 22.5 g (yield 49%) of 3-oxa-tricyclo[6.2.1.02,7 ]undec-4-ene; b.p. 35°-7°/0.5 Torr.

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