반응 #3121

반응 방정식

4-hydroxybenzaldehyde

1,3-dibromopropane

→

product

수율 76.0%

1,3-bis(4-formyl-phenoxy)propane

수율 76.0%

용매

potassium carbonate

DMF

반응 조건

후처리

1. 1
   온도under reflux
2. 2
   workup.ADDITIONThe reaction mixture was poured
3. 3
   workup.DISTILLATIONinto cold distilled water
4. 4
   기타to obtain a precipitate
5. 5
   여과After filtration and vacuum
6. 6
   기타drying the precipitate
7. 7
   기타the resultant was recrystallized in ethanol
8. 8
   기타to obtain the white product (XII-1)

실험 절차

10.0 g of 4-hydroxybenzaldehyde and 8.3 g of 1,3-dibromopropane were reacted for 24 hours in 6.2 g of potassium carbonate solution in 100 ml of DMF under reflux. The reaction mixture was poured into cold distilled water to obtain a precipitate. After filtration and vacuum drying the precipitate, the resultant was recrystallized in ethanol to obtain the white product (XII-1). The product yield was 76%.

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