반응 #311924

ord-3b57e06bcae3498eb36afe5a8b96656f

반응 방정식

O=C(CO)[C@@H](O)[C@H](O)[C@H](O)COP(=O)([O-])[O-].[Na+].[Na+]
disodium D-fructose-6-phosphate
→
O=C(CO)[C@@H](O)[C@H](O)[C@H](O)COP(=O)(O)O
above-identified complex
수율 93.5%
O=C(CO)[C@@H](O)[C@H](O)[C@H](O)COP(=O)(O)O
D-fructose-6-phosphate
수율 93.5%

반응물

—
cis-[Pt(NH3)2 (H2O)2 ](NO3)2
O=C(CO)[C@@H](O)[C@H](O)[C@H](O)COP(=O)([O-])[O-].[Na+].[Na+]
disodium D-fructose-6-phosphate

시약

없음

용매

O
water

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타It was collected
  2. 2
    세척washed by alternate centrifugation and resuspension
  3. 3
    기타dried

실험 절차

To 18.5 ml of 0.67 M cis-[Pt(NH3)2 (H2O)2 ](NO3)2, 4.5 grams of disodium D-fructose-6-phosphate were added. The solution was stoppered with a porous plug and stirred for 49 days. At the end of that time, a blue, water-insoluble precipitate had formed. It was collected, and then washed by alternate centrifugation and resuspension. The precipitate was vacuum dried to yield 3.6 grams of the above-identified complex.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04234499uspto-grants-1980_11