반응 #311923

ord-b494f5c26b6646f58665b9032e6da9f1

반응 방정식

O=[N+]([O-])O
nitric acid
[Na+].[OH-]
sodium hydroxide
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)COP(=O)([O-])[O-].[Na+].[Na+]
disodium D-glucose-6-phosphate
→
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)COP(=O)(O)O
D-glucose-6-phosphate

반응물

—
aqueous solution
O=[N+]([O-])O
nitric acid
[Na+].[OH-]
sodium hydroxide
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)COP(=O)([O-])[O-].[Na+].[Na+]
disodium D-glucose-6-phosphate
—
cis-[Pt(NH3)2 -(H2O)](NO3)2

시약

없음

용매

O
water
O
water

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타stirred for 42 days as in the previous examples

실험 절차

To 22.5 ml of a 0.67 M aqueous solution of cis-[Pt(NH3)2 -(H2O)](NO3)2, the pH of which had been adjusted to 4 with sodium hydroxide, there was added 4.23 grams disodium D-glucose-6-phosphate dissolved in 30 ml of water. The pH of the reaction mixture was then adjusted to 5.0 using 2 M nitric acid. The solution was stoppered, and stirred for 42 days as in the previous examples. The above-identified, water-soluble blue complex was isolated by the method described in Example 1 in a yield of 2.69 grams.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04234499uspto-grants-1980_11