반응 #311649

반응 방정식

sodium acetate

Boron trifluoride

2,3-dimethylhydroquinone

myristic acid

→

2,3-dimethyl-6-tetradecanoyl-hydroquinone

용매

methylene chloride

benzine

반응 조건

후처리

1. 1
   기타The methylene chloride was evaporated by means of steam
2. 2
   온도after cooling to a melt cake that
3. 3
   기타was isolated by decantation
4. 4
   workup.ADDITIONadded
5. 5
   여과The precipitate was filtered with suction
6. 6
   세척washed with benzine (boiling range: 50°-75° C.)
7. 7
   기타After being dried the precipitate
8. 8
   workup.STIRRINGwas stirred with acetonitrile
9. 9
   여과filtered with suction

실험 절차

Boron trifluoride was introduced with vigorous refluxing (bath temperature 50° C.) into a mixture of 138 g (1 mole) of 2,3-dimethylhydroquinone, 370 g (1.62 moles) of myristic acid and 700 ml of methylene chloride until saturation. After standing overnight the reaction mixture was decomposed by pouring into 3 l of a 10% by weight sodium acetate solution with stirring. The methylene chloride was evaporated by means of steam. The residual oily layer solidified after cooling to a melt cake that was isolated by decantation. It was melted up and added with stirring to 2 l of high-boiling benzine. The precipitate was filtered with suction and washed with benzine (boiling range: 50°-75° C.). After being dried the precipitate was stirred with acetonitrile and filtered with suction.

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