반응 #309608

반응 방정식

1,4-bis[(phenylmethyl)oxy]-2,3-naphthalenedicarboxylic acid

ethyl(4-aminophenyl)acetate

Water

→

title compound

수율 99.4%

Ethyl(4-{1,3-dioxo-4,9-bis[(phenylmethyl)oxy]-1,3-dihydro-2H-benzo[f]isoindol-2-yl}phenyl)acetate

수율 99.4%

용매

acetic acid

반응 조건

후처리

1. 1
   여과the solid collected by filtration
2. 2
   세척washed with water
3. 3
   기타This was dried under vacuum

실험 절차

A mixture of 1,4-bis[(phenylmethyl)oxy]-2,3-naphthalenedicarboxylic acid (2.0 g, 4.67 mmol) and ethyl(4-aminophenyl)acetate (1.67 g, 9.35 mmol) were heated to 120° C. in acetic acid (30 ml) for 2 hours. The mixture solidified on standing at room temperature overnight. Water was added and the solid collected by filtration and washed with water. This was dried under vacuum to give the title compound (2.65 g, 4.64 mmol). LC/MS: Rt=4.24, [MH]+ 572.

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