반응 #2681
ord-d5601d68778243e1afd472a048d0d106
반응 조건
온도
0°CELSIUS
상세 조건
See reaction.notes.procedure_details.
후처리
- 1온도to warm to room temperature
- 2기타The mixture was slowly quenched with 50 ml of water
- 3세척by washing with 1 liter of a 10% HCl solution
- 4건조The organic layer was dried with magnesium sulfate
- 5기타the solvent was evaporated
실험 절차
One mole of tri-n-decylmethylchloride was added to 0.75 liters of methylene chloride and the solution was blanketed with nitrogen and cooled to 0° C. 0.33 moles of trimethylaluminum was then added and the mixture was allowed to warm to room temperature. The mixture was slowly quenched with 50 ml of water followed by washing with 1 liter of a 10% HCl solution. The organic layer was dried with magnesium sulfate and the solvent was evaporated to give tri-n-decylmethylmethane after vacuum distillation at 225 C/0.5 torr. The yield was 75%.