반응 #2507815

반응 방정식

1,1,1,4,4-pentachloro-1,4-disilabutane

1,4-dioxane

→

1,1,1,4,4-pentachloro-1,4-disila-5-hexene

반응 조건

후처리

1. 1
   기타acetylene was bubbled to solution until it
2. 2
   기타The solution thus obtained
3. 3
   온도was slowly warmed up to room temperature
4. 4
   기타1,4-dioxane was evaporated

실험 절차

40.00 g (0.152 mol) 1,1,1,4,4-pentachloro-1,4-disilabutane was dissolved in 1000 ml 1,4-dioxane in a 2000 ml vessel. The solution was cooled down to 0° C. and acetylene was bubbled to solution until it was saturated. The solution thus obtained was slowly warmed up to room temperature. 1,4-dioxane was evaporated and obtained crude 1,1,1,4,4-pentachloro-1,4-disila-5-hexene was purified by distillation.

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