반응 #2503562

ord-d383c2f7b92b47d59fa7db5bf0e1b037

반응 방정식

O=C(Cl)C12CC3CC(O)(C1)CC(C(=O)Cl)(C3)C2
1,3-dichloroformyl-5-hydroxyadamantane
CN(C)C
trimethylamine
C[Si](C)(C)Cl
trimethylsilyl chloride
→
C[Si](C)(C)OC12CC3CC(C(=O)Cl)(C1)CC(C(=O)Cl)(C3)C2
1,3-dichloroformyl-5-trimethylsiloxyadamantane

반응물

O=C(Cl)C12CC3CC(O)(C1)CC(C(=O)Cl)(C3)C2
1,3-dichloroformyl-5-hydroxyadamantane
CN(C)C
trimethylamine
C[Si](C)(C)Cl
trimethylsilyl chloride

시약

없음

용매

ClCCl
methylene chloride

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타Reaction
  2. 2
    기타was carried out at room temperature

실험 절차

The 1,3-dichloroformyl-5-hydroxyadamantane was dissolved in methylene chloride. To this solution were added a small amount of trimethylamine, and then an equimolar amount of trimethylsilyl chloride. Reaction was carried out at room temperature to obtain 1,3-dichloroformyl-5-trimethylsiloxyadamantane.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US06824957B2uspto-grants-2004_11