반응 #2496

반응 방정식

4,4-di(1'-methylpropyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide

lithium aluminum hydride

→

2-di(1'-methylpropyl)phosphinomethyl-2'-methyl-1,1'-binaphthyl

용매

xylene

반응 조건

실험 절차

4 g (7.9 mmol) of 4,4-di(1'-methylpropyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide are suspended in 70 ml of absolute xylene and reacted with 400 mg (10.5 mmol) of lithium aluminum hydride using a method analogous to Example 5.

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