반응 #2470

ord-4de432ae17d04f5487e4f075f169e736

반응 방정식

CCCCC[C@@H]1[C@H](CC(=O)OC)CC[C@@H]1O
methyl (-)-(1S,2R,3S)-3-hydroxy-2-pentyl-1-cyclopentane acetate
→
CCCCC[C@H]1C(=O)CC[C@H]1CC(=O)OC
methyl (-)-(1S)-cis-3-oxo-2-pentyl-1-cyclopentaneacetate

반응물

CCCCC[C@@H]1[C@H](CC(=O)OC)CC[C@@H]1O
methyl (-)-(1S,2R,3S)-3-hydroxy-2-pentyl-1-cyclopentane acetate

시약

없음

용매

CO
methanol

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

The intermediate methyl (-)-(1S,2R,3S)-3-hydroxy-2-pentyl-1-cyclopentane acetate presented a [α]20D =-16° (c=1.805, methanol)

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05728866uspto-grants-1998_03